The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Aromatic compounds / Aromatic radicals / C6H5CH2O2 / ElDib(2006)_298K_220-280nm(class)

DATAFILE: C6H5CH2O2_ElDib(2006)_298K_220-280nm(class).txt
NAME: benzylperoxy radical
FORMULA: C6H5CH2O2
AUTHOR(YEAR): ElDib(2006)
T: 298K
λ: 220-280nm(class)
BIBLIOGRAPHY: G. El Dib, A. Chakir, E. Roth, J. Brion, and D. Daumont, "Study of benzylperoxy radical using laser photolysis: Ultraviolet spectrum, self-reaction, and reaction with HO2 kinetics", J. Phys. Chem. A 110, 7848-7857 (2006); DOI: 10.1021/jp056860p
COMMENTS: Photolysis of a slow flowing mixture of Cl2, N2, O2, and C6H5CH3

The absorption cross sections were determined by the classical method relative to the recommended σ(CH3CH2O2, 250 nm) = 4.12×10-18 cm2 molecule-1

The error limits of the absorption cross sections are listed in the third column of the datafile

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